TPU 68D Overview

TPU – 68D is a high-hardness thermoplastic polyurethane that combines flexibility, durability, and strong impact performance with a Shore hardness of 68D. It is suited to functional parts that require greater rigidity than soft TPU while retaining high elongation and energy absorption.

Design Advantages

  • High Shore hardness for semi-rigid parts that still require flexibility and recovery
  • Published X/Y elongation greater than 650% for highly deformable designs
  • Strong impact performance for protective, energy-absorbing, and wear-resistant components
  • Fast processing capability with reduced stringing compared with many softer TPU grades

Material Specifications

ItemPublished Value
Material familyThermoplastic polyurethane
Shore hardness68D
Filament diameter1.75 mm
Published density1.26 g/cm3
Water solubilityInsoluble
Appearance and odorSolid filament; odorless under normal handling

Material Properties

Physical and Thermal Properties

PropertyTest MethodPublished Value
DensityISO 11831.26 g/cm3
Melt index210 °C at 2.16 kg21.8 ± 0.3 g/10 min
Melting temperatureDSC at 10 °C/min183 °C
Glass transition temperatureDSC at 10 °C/minNot reported
Crystallization temperatureDSC at 10 °C/minNot reported
Vicat softening temperatureISO 306 and GB/T 1633Not reported
Heat deflection at 1.8 MPaISO 75Not reported
Heat deflection at 0.45 MPaISO 75Not reported
Saturated water absorption25 °C and 55% RH1.20%

Mechanical Properties

PropertyTest MethodPublished Value
Young’s modulus X/YISO 527 and GB/T 10401,190 ± 0.4 MPa
Young’s modulus ZISO 527 and GB/T 1040600 ± 0.5 MPa
Tensile strength X/YISO 527 and GB/T 104022.4 ± 0.6 MPa
Tensile strength ZISO 527 and GB/T 104011.2 ± 0.5 MPa
Elongation at break X/YISO 527 and GB/T 1040>650%
Elongation at break ZISO 527 and GB/T 104031%
Flexural modulus X/YISO 178 and GB/T 9341Not reported
Flexural modulus ZISO 178 and GB/T 9341Not reported
Flexural strength X/YISO 178 and GB/T 9341Not reported
Flexural strength ZISO 178 and GB/T 9341Not reported
Impact strength X/YISO 179 and GB/T 1043124.3 kJ/m2
Impact strength ZISO 179 and GB/T 10439.6 ± 0.3 kJ/m2

Processing

Recommended Processing Window

SettingRecommended Range
Drying before printingForced-air drying oven at 70 °C for 8 h
Printing and storage humidityBelow 20% RH; sealed with desiccant
Nozzle size0.4, 0.6, or 0.8 mm
Nozzle temperature220 to 240 °C
Build surfaceTextured PEI or smooth PEI with glue
Bed temperature30 to 35 °C
CoolingPart-cooling fan on
Printing speedBelow 250 mm/s
Retraction0.8 to 1.4 mm at 20 to 40 mm/s
Chamber temperature25 to 45 °C
Overhang and bridgingApproximately 70 degree maximum overhang; 20 mm maximum bridge
SupportsEnable where required by geometry

Representative Specimen Conditions

ParameterSource Condition
Nozzle temperature230 °C
Bed temperature35 °C
Printing speed130 mm/s
Infill density100%
Pre-test conditioningAnnealed and dried at 70 °C for 12 h

Chemical and Handling Characteristics

CharacteristicPublished Information
CompositionThermoplastic polyurethane
Odor and skin hazardsOdorless; source documentation reports no skin hazard
Chemical stabilityStable under normal storage and handling conditions
Water solubilityInsoluble
Acid and alkali resistanceNot resistant
Organic solvent resistanceNot resistant to some organic solvents
Oil and grease resistanceResistant to most kinds of oil and grease
FlammabilityFlammable
Combustion productsWater, carbon oxides, and nitrogen oxides; pungent odor

Design and Validation Considerations

  • Account for strong anisotropy: published tensile strength is 22.4 MPa in X/Y and 11.2 MPa in Z, while elongation is greater than 650% in X/Y and 31% in Z.
  • Use X/Y-oriented load paths where high elongation, toughness, and impact performance are critical.
  • Dry and store material below 20% RH with desiccant to support consistent extrusion and mechanical performance.
  • Do not assume chemical compatibility from the generic resistance statements; validate the actual fluid, concentration, temperature, exposure time, and stress state.
  • Annealing is generally not recommended because complex parts may deform. Do not use a microwave or household kitchen oven for drying or heat treatment.

Published Data and Qualification