PPA-CF Overview

PPA-CF is a carbon-fiber-reinforced, semi-aromatic nylon engineered for exceptional stiffness, strength, dimensional stability, and thermal performance. It is suited to demanding functional prototypes and end-use parts operating in humid or elevated-temperature environments.

Design Advantages

  • Very high X/Y stiffness and tensile strength for structural components
  • High heat-deflection and softening temperatures for demanding service
  • Improved moisture performance compared with general-purpose nylons
  • Broad resistance to weak acids, weak alkalis, solvents, oils, and greases

Material Specifications

ItemPublished Value
Material familySemi-aromatic nylon with carbon fiber
Filament diameter1.75 ± 0.05 mm
Published density1.25 g/cm3
Vicat softening temperature232 °C
Heat deflection temperature196 °C at 1.8 MPa; 227 °C at 0.45 MPa
Water solubilityInsoluble

Material Properties

Physical and Thermal Properties

PropertyTest MethodPublished Value
DensityISO 11831.25 g/cm3
Melt index280 °C at 2.16 kg8.4 ± 0.7 g/10 min
Melting temperatureDSC at 10 °C/min258 °C
Glass transition temperatureDSC at 10 °C/min85 °C
Crystallization temperatureDSC at 10 °C/min178 °C
Vicat softening temperatureISO 306 and GB/T 1633232 °C
Heat deflection at 1.8 MPaISO 75196 °C
Heat deflection at 0.45 MPaISO 75227 °C
Saturated water absorption25 °C and 55% RH1.30%

Mechanical Properties

PropertyTest MethodPublished Value
Young’s modulus X/YISO 527 and GB/T 104011,800 ± 670 MPa
Young’s modulus ZISO 527 and GB/T 10404,300 ± 340 MPa
Tensile strength X/YISO 527 and GB/T 1040168 ± 4 MPa
Tensile strength ZISO 527 and GB/T 104057 ± 5 MPa
Elongation at break X/YISO 527 and GB/T 10403.2 ± 0.4%
Elongation at break ZISO 527 and GB/T 10400.9 ± 0.2%
Flexural modulus X/YISO 178 and GB/T 93419,860 ± 480 MPa
Flexural modulus ZISO 178 and GB/T 93413,240 ± 360 MPa
Flexural strength X/YISO 178 and GB/T 9341208 ± 6 MPa
Flexural strength ZISO 178 and GB/T 934163 ± 4 MPa
Impact strength X/YISO 179 and GB/T 104341.7 ± 2.8 kJ/m2; notched 6.5 ± 2.3 kJ/m2
Impact strength ZISO 179 and GB/T 10434.3 ± 0.4 kJ/m2

Processing

Recommended Processing Window

SettingRecommended Range
Drying before printingForced-air drying oven at 100 to 140 °C for 8 to 12 h
Printing and storage humidityBelow 20% RH; sealed with desiccant
Nozzle temperature280 to 310 °C
Build surfaceSmooth or textured PEI surface with suitable adhesive
Bed temperature100 to 120 °C
Cooling fanOn; tune for geometry and layer bonding
Printing speedBelow 100 mm/s
Chamber temperature50 to 80 °C

Representative Specimen Conditions

ParameterSource Condition
Nozzle temperature290 °C
Bed temperature110 °C
Printing speed80 mm/s
Chamber temperature52 °C
Pre-test conditioningSpecimens were not annealed before testing

Chemical and Handling Characteristics

CharacteristicPublished Information
CompositionSemi-aromatic nylon
Chemical stabilityStable under normal storage and handling conditions
Water solubilityInsoluble
Acid and alkali resistanceResistant to weak acids and alkalis; not resistant to strong acids or alkalis
Organic solvent resistanceResistant to most organic solvents
Oil and grease resistanceResistant to most oils and greases
FlammabilityFlammable
Combustion productsWater, carbon oxides, and nitrogen oxides; pungent odor

Design and Validation Considerations

  • Design for anisotropy: published strength, elongation, and impact performance are lower in the Z direction than in X/Y.
  • Use X/Y-oriented load paths where maximum strength, ductility, and impact performance are important.
  • Dry and store material below 20% RH with desiccant; moisture can affect extrusion quality and finished-part performance.
  • Higher chamber temperature can improve properties, especially in Z; validate the selected process window.
  • Annealing at 120 to 140 C for 6 to 12 h may change properties and can reduce toughness or cause deformation; validate the specific geometry and process.
  • Confirm chemical compatibility, sustained-temperature behavior, creep, flammability, and safety-critical loads in the intended service environment.

Published Data and Qualification